Suppose that from each group of
s atoms of a metal sample, it is possible to remove
f
electrons. Consider a block of mass
m. Assume
M is the molecular mass of the metal.
What will be the charge of this block if we remove
f electrons?
Problem data:
- Mass of block: m;
- Molecular mass of metal: M;
- Electron fraction removed: \( \displaystyle \frac{f}{s}\;\frac{\text{electrons}}{\text{atoms}} \).
Solution
The total electric charge of a body is given by
\[
\begin{gather}
\bbox[#99CCFF,10px]
{Q=n_{e}\mathrm e} \tag{I}
\end{gather}
\]
where
ne is the number of electrons in the sample and e is the elementary charge.
The number of moles
n of a mass is given by
\[
\begin{gather}
\bbox[#99CCFF,10px]
{n=\frac{m}{M}} \tag{II}
\end{gather}
\]
The number of atoms
na in the copper contained in the block will be
\[
\begin{gather}
n_{a}=nN_{A} \tag{III}
\end{gather}
\]
where
NA is the number of
Avogadro, substituting the expression (III) in
(II), we have
\[
\begin{gather}
n_{a}=\frac{m}{M}N_{A}\;\text{atoms} \tag{IV}
\end{gather}
\]
As we removed
f electrons of each
s atoms, the total number of electrons removed from
the block will be
\[
\begin{gather}
n_{e}=n_{a}\frac{f}{s} \tag{V}
\end{gather}
\]
substituting the expression (IV) in (V), we have
\[
\begin{gather}
n_{e}=\left(\frac{m}{M}N_{A}\;\cancel{\text{atoms}}\right)\times \left(\frac{f}{s}\;\frac{\text{electrons}}{\cancel{\text{atoms}}}\right)\\
n_{e}=\frac{mN_{A}}{M}\frac{f}{s}\;\text{electrons} \tag{VI}
\end{gather}
\]
substituting the expression (VI) in (I), we obtain
\[
Q=\frac{mN_{A}}{M}\frac{f}{s}e
\]
\[ \bbox[#FFCCCC,10px]
{Q=\frac{mefN_{A}}{sM}}
\]